Chimera Diimine Ligands in Emissive [Cu(P^P)(N^N)][PF6] Complexes
نویسندگان
چکیده
منابع مشابه
Highly emissive platinum(II) complexes bearing carbene and cyclometalated ligands.
A series of heteroleptic platinum(II) complexes (1a-3a and 1b-3b) bearing a dicarbene ligand and a cyclometalated bidentate ligand have been prepared. Two of the complexes (1a and 3a) were characterized by X-ray diffraction analyses, confirming the square-planar structures. Detailed spectroscopic properties of the complexes have been studied, and two complexes, 3a and 3b bearing a carbene chela...
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A highly emissive copper(I) complex bearing (4R,5R)-(-)-4,5-bis(diphenylphosphinomethyl)-2,2-dimethyl-1,3-dioxolane (diop) and 2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline (dmpp), [Cu(dmpp)(diop)]PF6 (1·PF6), was newly synthesized. The quantum yield of the luminescence of 1·PF6 in degassed dichloromethane is 0.38, which is one of the highest values among all copper(I) complexes bearing two bid...
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Diimine and diamine ligands that are unable to coordinate to a single metal favour the formation of unusual, high-nuclearity Zn chlorometallate and palladium chloride complexes.
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A series of new Pt(II) diimine complexes with different carbazolyl-capped acetylide ligands (Pt-1–Pt-5) were synthesized and characterized. Their photophysical properties were investigated systematically via spectroscopic and theoretical methods. All complexes exhibit ligand-centered 1π,π* transitions in the UV region, and broad, structureless metal-to-ligand charge transfer (1MLCT)/ligand-to-l...
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ژورنال
عنوان ژورنال: Inorganics
سال: 2020
ISSN: 2304-6740
DOI: 10.3390/inorganics8050033